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Asian mock vipers of the genus Psammodynastes and African forest snakes of the genus Buhoma are two genera belonging to the snake superfamily Elapoidea. The phylogenetic placements of Psammodynastes and Buhoma within Elapoidea has been extremely unstable which has resulted in their uncertain and debated taxonomy. We used ultraconserved elements and traditional nuclear and mitochondrial markers to infer the phylogenetic relationships of these two genera with other elapoids. Psammodynastes, for which a reference genome has been sequenced, were found, with strong branch support, to be a relatively early diverging split within Elapoidea that is sister to a clade consisting of Elapidae, Micrelapidae and Lamprophiidae. Hence, we allocate Psammodynastes to its own family, Psammodynastidae new family. However, the phylogenetic position of Buhoma could not be resolved with a high degree of confidence. Attempts to identify the possible sources of conflict in the rapid radiation of elapoid snakes suggest that both hybridisation/introgression during the rapid diversification, including possible ghost introgression, as well as incomplete lineage sorting likely have had a confounding role. The usual practice of combining mitochondrial loci with nuclear genomic data appears to mislead phylogeny reconstructions in rapid radiation scenarios, especially in the absence of genome scale data.

The presence and behaviour of bivalves can affect the functioning of seafloor sediments through the irrigation of deeper strata by feeding and respiring through siphonal channels. Here, we investigated the physiological response and consecutive impact on functioning and body condition of the white furrow shell Abra alba in three pH treatments (pH = 8.2, pH = 7.9 and pH = 7.7). Although no pH effect on survival was found, lowered respiration and calcification rates, decreased energy intake (lower absorption rate) and increased metabolic losses (increased excretion rates) occurred at pH ~ 7.7. These physiological responses resulted in a negative Scope for Growth and a decreased condition index at this pH. This suggests that the physiological changes may not be sufficient to sustain survival in the long term, which would undoubtedly translate into consequences for ecosystem functioning.

Context The climate on Earth is changing due to the increased emissions of CO2 into the atmosphere, and these changes are expected to have a predominantly negative impact, with potentially dramatic economic, social and environmental consequences. The increased concentrations of CO2 are already resulting in acidification of the oceans, which adds further to the environmental pressure. Reducing the emissions of CO2 is therefore of prime importance. CO2 Capture and Storage (CCS) is considered as an essential element in the portfolio of measures, and has the potential to reduce the CO2 emissions from large industrial facilities to nearly zero. This has been recognised by the international community and especially Europe is being proactive in stimulating the development and implementation of CCS. Policy related research on CCS in Belgium has been centralised in the PSS-CCS projects (Policy Support System for Carbon Capture and Storage). Phase one (PSS-CCS I) started at the end of 2005 and the results were integrally published in 2009 (Piessens et al., 2009). This work was continued in the projects PSS-CCS II, the actual phase two, and the international valorisation project PSS-CCS BeNe which extended the scope to the Netherlands and created official bridges between the national CCS projects in Belgium and the Netherlands (CATO-2). Objectives From the start, the PSS-CCS projects (Policy Support System for Carbon Capture and Storage) have promised to provide detailed and objective insights in the role that CCS can play in the CO2 mitigation efforts of Belgium. Achieving this central objective is only possible by bringing together information, data and methodologies from widely different fields. The list below gives a brief overview of these activities, which have often resulted in deliverables which are usually to be regarded as important achievements in their own right. - Inventory of the industrial emission sources for CO2 in Belgium at plant and sector level, for providing an actual view on these emissions and the need to replace aging infrastructure. - Economic and technical analysis of the different technologies and their performance that allow capturing CO2 from power plants and other industrial facilities. - Development and calibration of a least-cost routing application for transport of CO2 by pipeline. - Summary of the geological data to identify geological reservoirs (aquifers and coal related storage options) that are potentially suited for geological storage of CO2. - Risk evaluation of different types of reservoirs and a techno-economic overview of the different techniques to monitor a CO2 reservoir. - Overview of the storage options in neighbouring countries accessible from Belgium, and an assessment on the domestic use of these reservoirs in those countries. - Analysis of the production, conversion and consumption of energy in Belgium using the TIMES-BE model, including CCS technologies. - Development of the PSS II simulator for detailed and ad-hoc predictions of CCS implementation in Belgium. - Evaluating the simulation results of the two models regarding the economic and environmental role that CCS can play under different scenarios. Conclusions The PSS-CCS projects have looked into the different, but related aspects of CCS. Capture of CO2 in the power sector is retaken and update in this report, but particular attention is given to how capture technologies can be integrated in industrial production processes. Particular attention is given to the production of cement, iron and steel, hydrogen, ammonia, refineries and industrial boilers, making this report a reference document for the capture from industrial sources. Cost estimates of those technologies are provided where possible, often indicating that capture can be more cost efficiently than in the power sector (e.g. steel, hydrogen...). For others, such as refineries, it may be quite challenging because of the complexity of such installations. The storage of CO2 is only of secondary importance when considering only costs, but is essential in the project planning and communication. This is why, now demonstration projects in neighbouring countries have become a reality, this topic is attracting an increasing amount of attention. This report in particularly looks at storage in coal bearing sequences by evaluating the different potential migration routes of CO2. In an attempt to quantify the amounts of CO2 that may migrate to the surface, a comparison is made with published estimates. Conservative estimates for leakage along abandoned wells would be below the health concentration of CO2, and vertical migration of CO2 in the Campine Basin in absence of such wells or conductive faults would be below meter scale at a 100y time resolution. Migration of CO2 out of the coal-bearing strata would be even more difficult, since coal acts as both a reservoir and seal, and additional sealing layers are present within the heterogeneous sequence. Nevertheless, as also required by European law, extensive monitoring is required. A portfolio of different technologies is required to achieve a the resolution required for confirming that CO2 is not leaking from the reservoir, leading to relatively high monitoring costs for small reservoirs or reservoirs with low injectivity. A comprehensive overview of the coal sequences in the Hainaut Basin indicates a storage potential of 500 to 700 Mt in this area. Injection strategies for coal are discussed acknowledging the geological particularities of this coal basin. The capacity of the Dinantian aquifer in this area is comparable to that of coal, but of particularly interest because of the high injectivity. The databases of the PSS simulator have been updated and extended according to the newly acquired data in this project, and have been calibrated for pipeline routing against confidential data from industry. Together with the important improvements, the current version (PSS II) produces realistic and reliable forecasts on power technologies based on coal, natural gas and biomass, as well as for the steel sector. PSS II is used in parallel with TIMES-BE, using large the same databases to make the results compatible. These models show that CCS will be a likely economic option in the power sector, but especially in industry. However, relatively high ETS prices for CO2 emissions are required to trigger large scale implementation of CCS in especially the power sector. An essential factor in assuring that very low emission targets are realised by 2050, a portfolio of technologies is required: if technologies are left out, the probability that the low targets are reached decreases dramatically. Technology lock-in additionally poses a real threat, but can be mitigated with appropriate policy measures. When it comes to storage, the development of domestic storage capacity is justified, although Belgium will additionally have to rely on the export of CO2. Contribution of the project in a context of scientific support to a sustainable development policy During the more or less five years during which the PSS-CCS projects have been active, they have been able to fill the need for information and follow-up on the topic of CCS in Belgium. This resulted in a large and active follow-up committee representing over 30 institutes, including many administrations and stakeholders that weigh on environmental and economic policy. The different valorisation events of the project were initially strongly focussed on the dissemination of correct and objective information on CCS, for which the international interest was strongly growing. This was in line with the activities within the project of which the earliest tasks were focussed on gathering and organising the data required for modelling the role of CCS. Energy models in Belgium were at that time also looking to include data on CCS technologies as a future option, leading to a direct feed of information into e.g. the Belgian TIMES- BE model. Also the reports of the Federal Planning Bureau (PRIMES model) cite PSS-CCS as a main reference. An important surge for information was during the preparation of the European CCS directive (Directive 2009/31/EC). Technical information regarded mainly the storage of CO2, the prime focus of the directive, but also the outlooks produced by the project were used to consider the scale and relevance of CCS for Belgium. Also other organisations and networks called upon the PSS-CCS partners for direct advice, or for presentations on the topic. The reader is referred to chapter 4 (DISSEMINATION AND VALORISATION) for an overview of the main and official valorisation activities originating from the PSS-CCS projects. Within Belgium and its regions, CCS is a well-known and documented option in mid- and long-term energy projections thanks to the catalytic role of the PSS-CCS projects. The now fully mature PSS II simulator and its databases currently play an important role in exchange activities with other countries through European collaboration and network projects (e.g. Welkenhuysen & Piessens, 2011b). This export of expertise may result in an impact in those countries, comparable to that of the PSS-CCS projects in Belgium.