Point source contaminations origin from historic or current activities and occur in a variety of forms, extents and contaminants involved (e.g. landfills, industrial facilities, storage tanks, disposal of hazardous waste). Point source contaminations may pose risks to human health and the environment; it is therefore important to develop/improve current methodologies to assess the migration potential of contaminants in groundwater. Groundwater quality monitoring around contaminated sites is typically done by sampling piezometers. Modelling approaches can help to predict the spatial and temporal evolution of contamination plumes, design remediation strategies and assess health and environmental risks. Reactive transport models can potentially improve the prediction of contaminant routes, as they explicitly account for changing geochemical environments and chemical reactions during transport. In spite of recent advances, real-world applications remain scarce as these require large numbers of site-specific parameters. The aim of the RESPONSE project is to improve the use of reactive transport models that simulate the fate of inorganic and organic contaminants in soils and groundwater. More specifically, this project aims to (1) identify the minimum amount of site-specific parameters needed to predict reactive transport of inorganic pollutants (e.g. heavy metals) and (2) improve/simplify the modelling of transport of xenobiotic organic contaminants (XOC, e.g. hydrocarbons and pesticides). The transport of XOCs is particularly complex to model due to the effects and zonation of microbial activity at the plume fringe in polluted aquifers. The RESPONSE project focusses on typical groundwater pollution problems encountered around old municipal landfill sites and cemeteries. Municipal landfills can still release hazardous pollutants such as heavy metals and XOCs, even if they are covered by fresh ground layers after abandonment. Cemeteries can be considered a special case of landfill, releasing various compounds to the environment such as arsenic, mercury, bacteria, viruses and herbicides. Both location types are potential point sources for mixed groundwater pollution, typically including high concentrations of dissolved organic carbon (DOC), heavy metals and XOCs. The methodology in this project involves both experimental and modelling aspects. During the first screening stage, groundwater samples were collected from shallow piezometers at fifteen contaminated sites across Belgium (municipal landfills and cemeteries). Also, an improved reactive transport model is built based on HYDRUS1D-MODFLOW-PHREEQC to explicitly account for the dynamic behaviour of chemical conditions at the soil-ground water interface. Next, based on laboratory analyses, three case-study sites will be selected for further modelling and testing.
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RBINS Staff Publications 2018
This study is concerned with the Late Holocene floodplain history of the Karkheh River in Lower Khuzestan, and in particular with the role of human action upon its channel shifts. The research was conducted in a multidisciplinary way, in which resources and approaches from different research fields were combined: (1) geomorphological mapping based on the interpretation of Landsat and CORONA satellite imagery, (2) analyses of geological sequences, including the identification of sedimentary facies and radiocarbon dating of organic material, (3) an archaeological field survey of ancient settlements, and (4) consultation of historical documents, mainly Arabic texts from the 9th–14th century and European travel literature from the 16th-early 20th century. Three main channel belts of the Karkheh were identified (labelled Kh1, Kh2 and Kh3), corresponding to successive stages in the evolution of the floodplain. Two river shifts are documented in the datasets, both taking place within the last 2000 years. The first avulsion regards a shift from channel belt Kh1, once a tributary of the Karun, to the straight river bed of Kh2, taking place at least after 1240–1310 cal BP/710–640 AD. The second avulsion, from Kh2 to Kh3, is clearly documented in historical sources and happened in a single night event in the year 1837/113 cal BP. Reactivation of the Kh2 river bed and its irrigation canals can be attributed to the recent construction of an artificial canal bypassing the second avulsion point. Both river shifts were strongly influenced by human interference, whereby an artificial irrigation canal took over the entire river flow from the main channel belt. Most likely, a combination of human-induced factors, such as weakening of the river levees, high sedimentation rates and disadvantageous channel gradients, led to a situation prone to avulsion.
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