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Competition between kaolinite flocculation and stabilization in divalent cation solutions dosed with anionic polyacrylamides
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Divalent cations have been reported to develop bridges between anionic polyelectrolytes and negatively-charged colloidal particles, thereby enhancing particle flocculation. However, results from this study of kaolinite suspensions dosed with various anionic polyacrylamides (PAMs) reveal that Ca2+ and Mg2+ can lead to colloid stabilization under some conditions. To explain the opposite but coexisting processes of flocculation and stabilization with divalent cations, a conceptual flocculation model with (1) particle-binding divalent cationic bridges between PAM molecules and kaolinite particles and (2) polymer-binding divalent cationic bridges between PAM molecules is proposed. The particle-binding bridges enhanced flocculation and aggregated kaolinite particles in large, easily-settleable flocs whereas the polymer-binding bridges increased steric stabilization by developing polymer layers covering the kaolinite surface. Both the particle-binding and polymer-binding divalent cationic bridges coexist in anionic PAM- and kaolinite-containing suspensions and thus induce the counteracting processes of particle flocculation and stabilization. Therefore, anionic polyelectrolytes in divalent cation-enriched aqueous solutions can sometimes lead to the stabilization of colloidal particles due to the polymer-binding divalent cationic bridges.
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RBINS Staff Publications
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The upper Eocene-Oligocene carnivorous mammals from the Quercy Phosphorites (France) housed in Belgian collections
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The Quercy Phosphorites Formation in France is world famous for its Eocene to Miocene faunas, especially those from the upper Eocene to lower Oligocene, the richest of all. The latter particularly helped to understand the ‘Grande Coupure’, a dramatic faunal turnover event that occurred in Europe during the Eocene-Oligocene transition. Fossils from the Quercy Phosphorites were excavated from the middle 19th century until the early 20th century in a series of sites and became subsequently dispersed over several research institutions, while often losing the temporal and geographical information in the process. In this contribution, we provide an overview and reassess the taxonomy of these barely known collections housed in three Belgian institutions: the Université de Liège, KU Leuven, and the Royal Belgian Institute of Natural Sciences. We focus our efforts on the carnivorous mammals (Hyaenodonta and Carnivoramorpha) and assess the stratigraphic intervals covered by each collection. These fossils are derived from upper Eocene (Priabonian), lower Oligocene (Rupelian), and upper Oligocene (Chattian) deposits in the Quercy area. The richness of the three collections (e.g., the presence of numerous postcranial elements in the Liège collection), the presence of types and figured specimens in the Leuven collection, and some identified localities in the RBINS collection make these collections of great interest for further studies on systematics and the evolution of mammals around the ‘Grande Coupure’.
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RBINS Staff Publications 2021
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Integration of landscape genomics, provenance trials and association mapping identifies genetic components underlying cold hardiness adaptation for coastal Douglas-fir (Pseudotsuga menziesii var. menziesii)
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RBINS Staff Publications 2018
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Noble gases in micrometeorites from the Transantarctic Mountains
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The bulk of extraterrestrial matter currently accreted by the Earth is in the form of micrometeorites (MMs) and interplanetary dust particles (IDPs), thus they may have collectively made a substantial contribution to the volatile inventory of the Earth and the other terrestrial planets. We have performed a complete noble gas study, accompanied by a complete petrographic characterization, of MMs from the Transantarctic Mountain (TAM) collection in the size range ∼300 to ∼1000 µm that fell over an extended time period during the last ∼1 Ma. Our noble gas study includes krypton and xenon, which have been largely missing in previous work. Helium and neon are dominated by a solar component, with generally lower abundance in scoriaceous MMs than in unmelted ones, and also generally lower in abundance than in previously studied MMs, which may be explained by the larger particle size (surface/volume ratio) of the MMs we studied. Considering an enhanced MM flux in the early Solar System, such MMs may have supplied a significant fraction of Earth’s neon. A number of MMs have kept what was probably their pre-terrestrial He/Ne ratio, from which we infer that the observed solar component is retained in a tiny surface region not affected by atmospheric entry. The abundances of (volume-correlated) heavier gases are similar to what was found in previous studies of smaller MMs. While Ar contains both solar and “planetary” contributions, the heavy noble gases (Kr, Xe) generally show “planetary” patterns but are often also compromised by terrestrial contamination as evidenced by an enhanced Kr/Xe ratio. Kr and Xe in a subset of scoriaceous MMs are dominated by isotopically fractionated air, possibly acquired during the passage through Earth’s ionosphere. Those not obviously affected by air show isotopic ratios similar to primitive meteorites (the Q component), thus primordial heavy gases supplied to the Earth by MMs are likely as those found in macroscopic meteorites. There is no evidence for the presence of a “cometary” Xe component as identified in the coma of comet 67P/Churyumov-Gerasimenko, hence a cometary source for a significant fraction of MMs in the studied size range is unlikely. Cosmogenic helium, neon and argon were detected in several cases. Cosmic ray exposure ages were calculated based on cosmogenic 21Ne in combination with the Poynting-Robertson effect, but depend on assumptions about atmospheric entry loss. Still, several cases are consistent with an origin from the asteroid belt (even assuming no loss) and one scoriaceous MM (#45b.17) would have to originate from beyond Jupiter. In at least two cases, including #45b.17, the isotopic composition of cosmogenic Ne appears to be inconsistent with predominant production in small particles free-floating in space, however; much of the irradiation of these MMs may have occurred when they were part of larger parent bodies.
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RBINS Staff Publications 2018
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Functional volumes, niche packing and species richness: biogeographic legacies in the Congo Basin
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RBINS Staff Publications 2020
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The phylogeny of the African wood mice (Muridae, Hylomyscus) based on complete mitochondrial genomes and five nuclear genes reveals their evolutionary history and undescribed diversity
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RBINS Staff Publications 2020
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Mainstreaming biodiversity conservation into development cooperation—highlights from an ALTER-NET-EKLIPSE workshop
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RBINS Staff Publications 2020
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The DeepMIP contribution to PMIP4: methodologies for selection, compilation and analysis of latest Paleocene and early Eocene climate proxy data, incorporating version 0.1 of the DeepMIP database.
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RBINS Staff Publications 2019
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A geological collection and methodology for tracing provenance of Palaeolithic colouring materials.
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Although prehistoric sites frequently contain numerous fragments and traces of many different kinds of colouring matter, intensive study of this type of archaeological remains began only recently. Such studies, aimed at determining how raw materials formed and changed over time, and how they were transported by the groups of humans who used them, are extremely valuable as they reveal shared strategies, that is, cultural traditions and the spaces in which they developed. The scope of this paper focusses on the description of the main geological contexts in which ferruginous colouring materials form and are found. In the framework of a collective research program called Pigmentothèque (iron- and manganese-rich rocks and minerals library), geological surveys are conducted taking into consideration the geological settings in which colouring materials are present and using a common record and sampling methodology which is followed by petrophysical, mineralogical and chemical analyses based on a shared procedure and vocabulary. In order to go beyond descriptions based solely on colour and chemical composition, we describe the great variety of iron-rich materials that can be used to obtain colouring matter. This diversity in the formation and evolution of iron-rich materials must be taken into account when trying to understand past humans’ choices of raw materials, their provenance and the anthropogenic and natural modifications they have undergone. We also describe criteria for recognising cohesive remains of colouring matter during archaeological excavations, so these artefacts can take their place alongside other mineral resources in helping improve our understanding of past societies.
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RBINS Staff Publications 2021
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The holothurian subgenus Mertensiothuria (Aspidochirotida: Holothuriidae) revisited.
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Mertensiothuria is one of the 20 subgenera currently recognized under Holothuria. The diagnosis of the subgenus is amended with new information on the ossicles found in the longitudinal muscles. The number of species of Mertensiothuria considered to be valid at present is six. These species are redescribed on the basis of new material, type and non-type museum material and on re-evaluation of literature. Two of them, Holothuria hilla and Holothuria aphanes, are transferred from the subgenus Thymiosycia to Mertensiothuria. Four species formerly referred to Mertensiothuria are removed; provisionally they are not referred to any of the known subgenera of Holothuria. Full annotated descriptions or (where the type material was not available) references to the literature are given for each species. An identification key is given to the species belonging to the subgenus Mertensiothuria.
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RBINS Staff Publications
